The representation of sediment source group tracer distributions in Monte Carlo uncertainty routines for fingerprinting: An analysis of accuracy and precision using data for four contrasting catchments     

Simon Pulley  Adrian L. Collins  J. Patrick Laceby 《水文研究》2020,34(11):2381-2400

Previous studies comparing sediment fingerprinting un-mixing models report large differences in their accuracy. The representation of tracer concentrations in source groups is perhaps the largest difference between published studies. However, the importance of decisions concerning the representation of tracer distributions has not been explored explicitly. Accordingly, potential sediment sources in four contrasting catchments were intensively sampled. Virtual sample mixtures were formed using between 10 and 100% of the retrieved samples to simulate sediment mobilization and delivery from subsections of each catchment. Source apportionment used models with a transformed multivariate normal distribution, normal distribution, 25th–75th percentile distribution and a distribution replicating the retrieved source samples. The accuracy and precision of model results were quantified and the reasons for differences were investigated. The 25th–75th percentile distribution produced the lowest mean inaccuracy (8.8%) and imprecision (8.5%), with the Sample Based distribution being next best (11.5%; 9.3%). The transformed multivariate (16.9%; 17.3%) and untransformed normal distributions (16.3%; 20.8%) performed poorly. When only a small proportion of the source samples formed the virtual mixtures, accuracy decreased with the 25th–75th percentile and Sample Based distributions so that when <20% of source samples were used, the actual mixture composition infrequently fell outside of the range of uncertainty shown in un-mixing model outputs. Poor performance was due to combined random Monte Carlo numbers generated for all tracers not being viable for the retrieved source samples. Trialling the use of a 25th–75th percentile distribution alongside alternatives may result in significant improvements in both accuracy and precision of fingerprinting estimates, evaluated using virtual mixtures. Caution should be exercised when using a normal type distribution, without exploration of alternatives, as un-mixing model performance may be unacceptably poor.  相似文献   

Variation in mantle lithology and composition beneath the Ngao Bilta volcano,Adamawa Massif,Cameroon volcanic line,West-central Africa     

Robert Temdjim  Merlin Patrick Njombie Wagsong  Arnold Julien Nzakou Tsepeng  Stephen Foley 《地学前缘(英文版)》2020,(2):665-677

Mantle peridotites entrained as xenoliths in the lavas of Ngao Bilta in the eastern branch of the continental Cameroon Line were examined to constrain mantle processes and the origin and nature of melts that have modified the upper mantle beneath the Cameroon Line.The xenoliths consist mainly of lherzolite with subordinate harzburgite and dunite.They commonly contain olivine,orthopyroxene,clinopyroxene and spinel although the dunite is spinel-free.Amphibole is an essential constituent in the lherzolites.Mineral chemistry differs between the three types of peridotite:olivines have usual mantle-like Mg#of around 90 in lherzolites,but follow a trend of decreasing Mg#(to 82)and NiO(to 0.06 wt.%)that is continuous in the dunites.Lherzolites also contain orthopyroxenes and/or clinopyroxenes with low-Mg#,indicating a reaction that removes Opx and introduces Cpx,olivine,amphibole and spinel.This is attributed to reaction with a silica-undersaturated silicate melt such as nephelinite or basanite,which originated as a low-degree melt from a depleted source as indicated by low Al2O3 and Na2O in Cpx and high Na2O/K2O in amphibole.Thermobarometric estimates place the xenoliths at pressures of 11–15 kbar(35–50 km)and temperatures of 863–957
C,along a dynamic rift geotherm and shallower than the region where carbonate melts may occur.The melt/rock reactions exhibited by the Ngao Bilta xenoliths are consistent with their peripheral position in the eastern branch of the Cameroon Volcanic Line in an area of thinned crust and lithosphere beneath the Adamawa Uplift.  相似文献   

Reconstruction of the Late Holocene climate and environmental history from North Bolgoda Lake,Sri Lanka,using lipid biomarkers and pollen records     

Kasun Gayantha  Joyanto Routh  Krishnamurthy Anupama  Jean Lazar  Srinivasan Prasad  Rohana Chandrajith  Patrick Roberts  Gerd Gleixner 《第四纪科学杂志》2020,35(4):514-525

The catastrophic impact and unpredictability of the Indian Ocean Monsoon (IOM) over South Asia are evident from devastating floods, mudslides and droughts in one of the most densely populated regions of the globe. However, our understanding as to how the IOM has varied in the past, as well as its impact on local environments, remains limited. This is particularly the case for Sri Lanka, where erosional landscapes have limited the availability of well-stratified, high-resolution terrestrial archives. Here, we present novel data from an undisturbed sediment core retrieved from the coastal Bolgoda Lake. This includes the presentation of a revised Late Holocene age model as well as an innovative combination of pollen, source-specific biomarkers, and compound-specific stable carbon isotopes of n-alkanes to reconstruct the shifts in precipitation, salinity and vegetation cover. Our record documents variable climate between 3000 years and the present, with arid conditions c. 2334 and 2067 cal a bp. This extreme dry period was preceded and followed by more wet conditions. The high-resolution palaeoenvironmental reconstruction fills a major gap in our knowledge on the ramifications of IOM shifts across South Asia and provides insights during a time of major redistribution of dense human settlements across Sri Lanka.  相似文献   

Ba- and Ti-rich oxymica from nephelinites in the Middle Atlas Volcanic Province,northern Morocco     

Lakroud  Kawtar  Remmal  Toufik  Makhoukhi  Samira  Balcone-Boissard  Hélène 《Mineralogy and Petrology》2020,114(2):119-128

Mineralogy and Petrology - A Ba- and Ti-rich mica (up to 14.0&nbsp;wt% BaO and 13.1&nbsp;wt% TiO2) occurs in nephelinites from the Middle Atlas Volcanic Province, Morocco. The rocks show a...  相似文献   

Solute concentrations of overland flow water in a cultivated field: spatial variations,intra‐ and inter‐storm trends     

Patrick Durand  Sylvie Cros‐Cayot  Chantal Gascuel‐Odoux  Djilali Heddadj 《水文研究》1999,13(10):1465-1477

Major solute concentrations in overland flow water (OFW) were measured in an agricultural field of Brittany (western France). Two storm events were monitored in detail to examine the short time‐scale processes. During one year, samples were taken at different positions on the slope after each storm event to describe the spatial and seasonal variations of OFW chemistry. Although the total dissolved load in OFW is not much higher than in rain water, distinctive features are observed. K⁺, Ca²⁺, NH₄ , Cl⁻ and SOare the major solutes. The main origin of the elements (sea salts, exchangeable soil complex or fertilizers) determined most of the variations observed. Spatial variations along the slope are mainly seen for exchangeable cations, while seasonal variations are predominant for sea salts. Rainfall intensity and suspended sediment load induce strong differences between the two storm events studied in detail. However, the within‐storm variations and the seasonal monitoring show that this relationship is complex. Within‐storm variations suggest that, in addition to desorption processes, mixing with pre‐event water may occur. The lack of a relationship between sediment load and dissolved load is attributed to the high rate of the exchange processes, which has been checked by a simple experiment in vitro. It is concluded that the conditions of the transit of water on the field (velocity, length, status of the surface, crusted or not) may well play a major role in the chemical changes between rain water and OFW. The results suggest that vegetated buffer strips designed to reduce the sediment load only, and not the amount of overland flow, will have little effect on the transfer of dissolved pollutants to the watercourses. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Partial integer decorrelation: optimum trade-off between variance reduction and bias amplification   总被引：2，自引：2，他引：0  

Patrick Henkel  Christoph Günther 《Journal of Geodesy》2010,84(1):51-63

Different techniques have been developed for determining carrier phase ambiguities, ranging from float approximations to the efficient solution of the integer least square problem by the LAMBDA method. The focus so far was on double-differenced measurements. Practical implementations of the LAMBDA method lead to a residual probability of wrong fixing of the order one percent. For safety critical applications, this probability had to be reduced by eight orders of magnitude, which could be achieved by linear multi-frequency code–carrier combinations. Scenarios with single or no differences include biases due to orbit errors, satellite clock offsets, as well as residual code and phase biases. For this case, a linear combination of Galileo E1 and E5 code and carrier phase measurements with a wavelength of 3.285 m and a noise level of a few centimeters is derived. This ionosphere-free combination preserves the orbit and clock errors, and suppresses the E1 code multipath by 12.6 dB. Since integer decorrelation transformations, as used in the LAMBDA method, inflate biases, the number of such transformations must be limited, and applied in a judicious order. With a Galileo type constellation, this leads to a vertical standard deviation of ca. 20 cm, while keeping the probability of wrong fixing extremely low for code biases of 10 cm, and phase biases of 0.1 cycle, combined in a worst case.  相似文献   

Initiativen zur marinen Naturstoffforschung in Deutschland     

Zeeck  A.  Bach  G. 《Ocean Dynamics》1999,51(10):91-95

Ocean Dynamics - Meeresorganismen werden als Quelle für neue Werk- und Wirkstoffe entdeckte. Mit zwei Initiativen, dem niedersächsischen “Forschungsschwerpunkt...  相似文献   

Temporal and spatial variability of extreme river flow quantiles in the Upper Vistula River basin,Poland          下载免费PDF全文

Agnieszka Rutkowska  Patrick Willems  Charles Onyutha  Wojciech Młocek 《水文研究》2017,31(7):1510-1526

Temporal and spatial variability in extreme quantile anomalies of seasonal and annual maximum river flows was studied for 41 gauging stations at rivers in the Upper Vistula River basin, Poland. Using the quantile perturbation method, the temporal variability in anomalies was analysed. Interdecadal oscillating components were extracted from the series of anomalies using the Hilbert‐Huang transform method. Period length, part of variance of each component, and part of unexplained variance were assessed. Results show an oscillating pattern in the temporal occurrence of extreme flow quantiles with clusters of high values in the 1960–1970s and since the late 1990s and of low values in the 1980s and at the beginning of the 1990s. The anomalies show a high variability on the right bank of the Upper Vistula River basin during the summer season with the highest values in catchments located in the western and south‐western parts of the basin. River flow extreme quantiles were found to be associated with large‐scale climatic variables from the regions of the North Atlantic Ocean, Scandinavia, Eastern Europe, Asia, and, to a lesser extent, the Pacific Ocean. Similarities between temporal variability of river flows and climatic factors were revealed. Results of the study are important for flood frequency analysis because a long observation period is necessary to capture clusters of high and low river flows.  相似文献   

High-Reflectivity Coatings for a Vacuum Ultraviolet Spectropolarimeter     

Noriyuki Narukage  Masahito Kubo  Ryohko Ishikawa  Shin-nosuke Ishikawa  Yukio Katsukawa  Toshihiko Kobiki  Gabriel Giono  Ryouhei Kano  Takamasa Bando  Saku Tsuneta  Frédéric Auchère  Ken Kobayashi  Amy Winebarger  Jim McCandless  Jianrong Chen  Joanne Choi 《Solar physics》2017,292(3):40

Precise polarization measurements in the vacuum ultraviolet (VUV) region are expected to be a new tool for inferring the magnetic fields in the upper atmosphere of the Sun. High-reflectivity coatings are key elements to achieving high-throughput optics for precise polarization measurements. We fabricated three types of high-reflectivity coatings for a solar spectropolarimeter in the hydrogen Lyman-\(\upalpha \) (Ly\(\upalpha \); 121.567 nm) region and evaluated their performance. The first high-reflectivity mirror coating offers a reflectivity of more than 80 % in Ly\(\upalpha \) optics. The second is a reflective narrow-band filter coating that has a peak reflectivity of 57 % in Ly\(\upalpha \), whereas its reflectivity in the visible light range is lower than 1/10 of the peak reflectivity (\(\sim 5~\%\) on average). This coating can be used to easily realize a visible light rejection system, which is indispensable for a solar telescope, while maintaining high throughput in the Ly\(\upalpha \) line. The third is a high-efficiency reflective polarizing coating that almost exclusively reflects an s-polarized beam at its Brewster angle of 68° with a reflectivity of 55 %. This coating achieves both high polarizing power and high throughput. These coatings contributed to the high-throughput solar VUV spectropolarimeter called the Chromospheric Lyman-Alpha SpectroPolarimeter (CLASP), which was launched on 3 September, 2015.  相似文献   

Late Wisconsinan deglaciation and proglacial lakes development in the Charlevoix region,southeastern Québec,Canada          下载免费PDF全文

Etienne Brouard  Patrick Lajeunesse  Pierre A. Cousineau  Étienne Govare  Jacques Locat 《Boreas: An International Journal of Quaternary Research》2016,45(4):754-772

The Charlevoix region, in southeastern Québec, is characterized by a dramatic landscape formed by the junction of the Laurentian Highlands, the Charlevoix Astrobleme and the St Lawrence Estuary. At the Last Glacial Maximum (LGM), the region was completely covered by the Laurentide Ice Sheet (LIS). The complex topography of the region was the stage of many of the major deglacial events of southern Quebec (e.g. Goldthwait Sea Invasion, St Lawrence Ice‐Stream, Saint‐Narcisse Episode). We present a detailed reconstruction of the pattern of retreat of the LIS in the Charlevoix region based on the interpretation of ice‐marginal features (e.g. moraines, fans) and glaciolacustrine landforms and deposits, two extensive field campaigns, and the interpretation of high‐resolution 3D digital aerial photographs and LiDAR data. Our results indicate five moraine complexes in the region: the Rochette, the Brûlée, the Sainte‐Anne, the Saint‐Narcisse and the Mars‐Batiscan complexes. Deltas, fans, fine‐grained sediments, littoral deposits, drainage breaches and deposits were used to identify 91 palaeo‐proglacial lakes. The identification of these lakes and their relation to moraine complexes enabled the reconstruction of six stages of lake development during the Charlevoix deglaciation. The development of proglacial lakes occurred in all types of terrain (highlands, lowlands, transitory levels above marine limit). We conclude that local topography had a decisive effect on promoting both moraine deposition and lake development. We suggest that similar topographical regions (hilly‐mountainous) that were affected by major ice‐margin stabilizations during glacial retreat should have experience small lakes dominating valleys and topographical lows.  相似文献